Phase rule classification of physical and chemical critical effects in liquid mixtures
| Autor: | Xingjian Wang, Pauline Norris, Joshua R. Lang, James K. Baird |
|---|---|
| Rok vydání: | 2019 |
| Předmět: |
Materials science
Critical phenomena General Physics and Astronomy Thermodynamics 02 engineering and technology 010402 general chemistry 021001 nanoscience & nanotechnology 01 natural sciences Chemical reaction Heat capacity Thermal expansion 0104 chemical sciences symbols.namesake Extent of reaction Critical point (thermodynamics) Phase rule symbols Isobaric process Physical and Theoretical Chemistry 0210 nano-technology |
| Zdroj: | Chemical Physics Letters. 729:73-78 |
| ISSN: | 0009-2614 |
| DOI: | 10.1016/j.cplett.2019.05.020 |
| Popis: | The isobaric heat capacity and the coefficient of thermal expansion of a binary liquid mixture with a critical point of solution diverge as functions of temperature in the critical region. When the same liquids are used as solvents for chemical reactions, the van’t Hoff plot of the extent of reaction diverges in the critical region. According to the phase rule, the physical and chemical properties are isomorphic in the sense that in each case the critical behavior is determined by three fixed thermodynamic intensive variables. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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