Absorption spectroscopy based high-speed oxygen concentration measurements at elevated gas temperatures

Autor: William P. Partridge, Samuel C. Geckler, Anthony Kyle Perfetto, Gurneesh S. Jatana
Rok vydání: 2019
Předmět:
Zdroj: Sensors and Actuators B: Chemical. 293:173-182
ISSN: 0925-4005
DOI: 10.1016/j.snb.2019.04.143
Popis: A sensor based on tunable diode laser absorption spectroscopy (TDLAS) has been developed for concentration measurements in high-temperature (up to 800 K) gas streams; while the sensor measures gas oxygen and water concentration, temperature and pressure, this work focuses on the challenges and solutions to transient oxygen measurement. A 760-nm diode laser was used to probe a pair of oxygen absorption transitions, and a Herriott cell based multi-pass arrangement was utilized to compensate for the extremely weak oxygen absorption as well as the high gas temperature. This multi-pass arrangement provides a 4297.4-mm absorption path length across a 76.2-mm diameter duct, and an O2 detection limit ([O2] where SNR=1) of ca. 0.1%. Laboratory validation of the HITRAN spectral parameters of the chosen absorption transitions was performed over a range of high temperatures and oxygen concentrations relevant to engine-exhaust applications. The insensitivity of the Herriott cell arrangement to vibrations and spatial temperature gradients was demonstrated. Results from applications to single- and multi-cylinder engine exhaust are presented and demonstrate the new sensor’s ability to measure fast intra-cycle gas-property transients, and provide insights relevant to advancing internal-combustion-engine technology.
Databáze: OpenAIRE
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