Transition metal decorated Ferrosoferric oxide (Fe3O4): An expeditious catalyst for photodegradation of Carbol Fuchsin in environmental remediation
| Autor: | Prashant Bhimrao Koli, Kailas Haribhau Kapadnis, Uday Gangadhar Deshpande |
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| Rok vydání: | 2019 |
| Předmět: |
Materials science
Dopant Process Chemistry and Technology Iron oxide 02 engineering and technology 010501 environmental sciences 021001 nanoscience & nanotechnology 01 natural sciences Pollution Nanomaterial-based catalyst Catalysis chemistry.chemical_compound chemistry Photocatalysis Chemical Engineering (miscellaneous) Carbol fuchsin 0210 nano-technology Photodegradation Waste Management and Disposal Iron oxide nanoparticles 0105 earth and related environmental sciences Nuclear chemistry |
| Zdroj: | Journal of Environmental Chemical Engineering. 7:103373 |
| ISSN: | 2213-3437 |
| DOI: | 10.1016/j.jece.2019.103373 |
| Popis: | In this research, we report the removal of Carbol Fuchsin dye by using doped Ferrosoferric oxide nanocatalyst. The nanocatalysts Fe3O4 and doped Fe3O4 was characterized by various methods. The structural properties of the prepared Fe3O4 doped Fe3O4 were investigated by using X-Ray Diffractometer (XRD), which confirmed the single-phase Fe3O4 nanoparticles. The surface, texture, morphology of nanoparticles was identified, from SEM. The crystal lattice confirmed from TEM. The magnetic property of Fe3O4 was confirmed by VSM analysis. The elemental composition of prepared pure and doped Ferrosoferric oxide was confirmed by EDS study. The zeta potential was investigated for the stability of iron oxide nanoparticles. XPS spectrum of doped Fe3O4 was analysed to find the surface characteristics and elemental composition of doped Fe3O4 nanocatalyst. Here undoped Fe3O4 and doped Fe3O4 were comparatively investigated for the Carbol Fuchsin dye degradation study. Different parameters like initial catalyst dose, the effect of pH, contact time, dye concentration, effect of dopants, catalyst recycling have been studied to optimize degradation study. The optimum conditions for the removal of the Carbol Fuchsin dye are found to be initial concentration 20 mg/L, photocatalyst dose 8 gm/L, pH 8.0. In kinetics study, Pseudo First order kinetics has been investigated for both pure and doped Ferrosoferric oxide catalyst. Almost 97% of dye degradation has been observed for doped iron oxide. |
| Databáze: | OpenAIRE |
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