Reactions of acylzirconocene chloride with nucleophiles: bimodal reactivity at β- and acyl carbons of α,β-unsaturated acylzirconocene chloride

Autor:	Akito Kakuuchi, Kensuke Narita, Takeo Taguchi, Yuji Hanzawa
Rok vydání:	2000
Předmět:	chemistry.chemical_classification Ketone chemistry Nucleophile Organic Chemistry Drug Discovery medicine Reactivity (chemistry) Biochemistry Medicinal chemistry Chloride medicine.drug
Zdroj:	Tetrahedron Letters. 41:7525-7528
ISSN:	0040-4039
DOI:	10.1016/s0040-4039(00)01291-0
Popis:	Reactions of α,β-unsaturated acylzirconocene chloride with nucleophiles showed novel bimodal reactivity at the β- and acyl carbons depending upon the nucleophile employed, and the formation of ketone α,β-dianionic species was also observed.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::d8d2cd180ecf5138d84c30ebb069aafc https://doi.org/10.1016/s0040-4039(00)01291-0 Zobrazit plný text záznamu Full Text from ScienceDirect