Pyrolysis of triphenyl (diphenoxyphosphinyl)phosphorimidate

Autor:	Hiroyuki Morita, Choichiro Shimasaki, Seichi Rengakuji, Toshiaki Yoshimura, Shin Ono, Kazuhiko Fukushima, Yuuko Nakamura, Minori Yonezawa
Rok vydání:	1998
Předmět:	Analytical chemistry Infrared spectroscopy Mass spectrometry High-performance liquid chromatography Analytical Chemistry chemistry.chemical_compound Fuel Technology chemistry Mass spectrum Phenol Pyrolysis Phosphazene Triphenyl phosphate Nuclear chemistry
Zdroj:	Journal of Analytical and Applied Pyrolysis. 45:41-58
ISSN:	0165-2370
Popis:	The pyrolysis of triphenyl (diphenoxyphosphinyl)phosphorimidate ( 1 ) was investigated using differential thermal analysis-thermogravimetry (DTA-TG), thermogravimetry-mass spectrometry (TG-MS), infrared spectroscopy (IR), mass spectrometry (MS), high performance liquid chromatography (HPLC) and the 31 P nuclear magnetic resonance method ( 31 P NMR). The cleavage of 1 by electron impact (EI) was also investigated, the results were used to elucidate the pyrolysis process. Compound 1 decomposed on heating to form phenol, triphenyl phosphate, hexaphenoxycyclotriphosphazene, octaphenoxycyclotetraphosphazene, triphenyl [ N -(diphenoxyphosphinyl)- P , P -diphenoxyphosphinimyl]phosphorimidate and longer-chain phosphazene compound (PhO) 2 P(O)NP(OPh) 2 NP(OPh) 2 NP(OPh) 3 . In mass spectrometric analysis, 1 was cleaved by the elimination of a phenoxyl radical, similar to pyrolysis, the formation of the ion assigned to triphenyl phosphate was observed.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::d8a09407a18b9b0483e099cd62029100 https://doi.org/10.1016/s0165-2370(97)00083-1 Zobrazit plný text záznamu Full Text from ScienceDirect