Synthesis of Diporphyrins by Oxidative Coupling with Pd(TFA)2-Cu(OTf)2 under Ball-Milling Conditions

Autor:	Xiuqiang Lu, Guofen Chen, Fei Li
Rok vydání:	2021
Předmět:	Green chemistry Chemistry Mechanochemistry Organic Chemistry Polymer chemistry Oxidative coupling of methane Ball mill Catalysis
Zdroj:	Synthesis. 53:2651-2655
ISSN:	1437-210X 0039-7881
DOI:	10.1055/a-1477-4371
Popis:	A sustainable synthetic method for the synthesis of diporphyrins under ball-milling conditions is reported. The meso-meso linked diporphyrins are efficiently accessed by direct oxidative homo-coupling of porphyrins with Pd(TFA)2 as the catalyst and Cu(OTf)2 as the oxidant.
Databáze:	OpenAIRE
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