Luminescent sensing of Cu 2+ , CrO 4 2− and photocatalytic degradation of methyl violet by Zn(II) metal-organic framework (MOF) having 5,5′-(1H-2,3,5-triazole-1,4-diyl)diisophthalic acid ligand
| Autor: | Abhinav Kumar, Bao-Hong Li, Chuying Gu, Wei-Ping Wu, Amita Singh, Jun Wang |
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| Rok vydání: | 2017 |
| Předmět: |
Ligand
Organic Chemistry Triazole Methyl violet 02 engineering and technology 010402 general chemistry 021001 nanoscience & nanotechnology Photochemistry 01 natural sciences Fluorescence 0104 chemical sciences Analytical Chemistry Inorganic Chemistry Metal chemistry.chemical_compound chemistry visual_art visual_art.visual_art_medium Photocatalysis Metal-organic framework 0210 nano-technology Luminescence Spectroscopy |
| Zdroj: | Journal of Molecular Structure. 1148:531-536 |
| ISSN: | 0022-2860 |
| DOI: | 10.1016/j.molstruc.2017.07.083 |
| Popis: | A porous Zn(II) metal–organic framework (MOF) [Zn(H2L)(4,4′-bipy)0.5]n (1) has been selected and its luminescence sensing for cations and anions as well as the photocatalytic property against methyl violet have been explored. Luminescence studies indicated that 1 could be an efficient multifunctional fluorescent material for highly sensitive detection of metal cation Cu2+ and anions CrO42−. The luminescence intensity of 1 was found to decrease proportionately with increase in the concentration of Cu2+ and CrO42−. Furthermore, the photocatalytic property of 1 for degradation of the methyl violet (MV) have been explored and a possible photocatalytic mechanism have been proposed using density of states (DOS) and partial DOS (pDOS) calculations. |
| Databáze: | OpenAIRE |
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