Formal [2 + 2 + 2] Cycloaddition Reaction of a Metal–Carbyne Complex with Nitriles: Synthesis of a Metallapyrazine Complex

Autor:	Haiping Xia, Jianfeng Lin, Hong Zhang, Qingde Zhuo, Linting Ding
Rok vydání:	2019
Předmět:	Inorganic Chemistry chemistry.chemical_compound 010405 organic chemistry Chemistry Organic Chemistry Polymer chemistry Carbyne Physical and Theoretical Chemistry 010402 general chemistry Triple bond 01 natural sciences Cycloaddition 0104 chemical sciences
Zdroj:	Organometallics. 38:2264-2271
ISSN:	1520-6041 0276-7333
DOI:	10.1021/acs.organomet.9b00213
Popis:	Although alkynes have been extensively exploited in [2 + 2 + 2] cycloadditions with nitriles to form N-heterocyclic aromatics, the “alkyne-like” metal–carbon triple bond has never been used in [2 +...
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::d87deaef7b61d10346bcad392ba05387 https://doi.org/10.1021/acs.organomet.9b00213 Zobrazit plný text záznamu