Triisobutylaluminium-promoted formation of lanthanide hydrides

Autor:	Eric C. Moinet, Olivier Tardif, Cäcilia Maichle-Mössmer, Reiner Anwander
Rok vydání:	2023
Předmět:	Materials Chemistry Metals and Alloys Ceramics and Composites General Chemistry Catalysis Surfaces Coatings and Films Electronic Optical and Magnetic Materials
Zdroj:	Chemical Communications. 59:5261-5264
ISSN:	1364-548X 1359-7345
DOI:	10.1039/d3cc01330h
Popis:	Treatment of homoleptic silylamide Ln[N(SiMe3)2]3 with TIBA affords distinct heteroaluminato ligands revealing both Ln(iii)-amido→Ln(iii)-alkyl and Ln(iii)-amido→Ln(iii)-hydrido transformations.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::d84f1693665d109ca6d62236b287224a https://doi.org/10.1039/d3cc01330h Zobrazit plný text záznamu