Night-time NO3and OH radical concentrations in the United Kingdom inferred from hydrocarbon measurements

Autor: P. D. Hamer, Dudley E. Shallcross, Carlos E. Canosa-Mas, M. J. Ashfold, L.A. Watson, Richard P. Wayne, Damien Martin, Graham Nickless, Mubarak A. Khan
Rok vydání: 2008
Předmět:
Zdroj: Atmospheric Science Letters. 9:140-146
ISSN: 1530-261X
DOI: 10.1002/asl.175
Popis: The hydrocarbon decay method (Rivett et al., 2003) has been used to analyse hydrocarbon data from four contrasting sites in the United Kingdom to estimate night-time levels of NO3 and OH. Remarkably consistent results emerge using alkenes, revealing NO3 and OH levels in the range of 0.01–10 ppt and 1 × 104 − 1 × 106 molecule cm−3, respectively. Weak seasonal cycles are observed where NO3 levels peak in spring and OH in summer. Analysis using alkanes suggests that Cl atom levels of around 2 × 104 molecule cm−3 may be present. How Cl may be formed at night in such high quantities is unknown and may not be the answer to the disparity between the two methods. Copyright © 2008 Royal Meteorological Society
Databáze: OpenAIRE