Synthesis, Characterization, Reactivity of η 3-allylPd(L)(X), Where X = Cl and L = Imidazolylphosphine and Their Application in Aryl Amination Reactions

Autor:	Gulin Erdogan, Reji N. Nair, Christoffel van Niekerk, Douglas B. Grotjahn
Rok vydání:	2014
Předmět:	Proton Dimer chemistry.chemical_element General Chemistry Medicinal chemistry Chloride Nitrogen Catalysis chemistry.chemical_compound chemistry medicine Organic chemistry Reactivity (chemistry) Aryl amination medicine.drug Palladium
Zdroj:	Topics in Catalysis. 57:1539-1544
ISSN:	1572-9028 1022-5528
Popis:	Synthesis of new mono-(imidazolylphosphine) palladium chloride complexes is reported. Imidazolyl phosphines reacted with allypalladium chloride dimer to form monophosphine palladium(II) complexes. Some of these complexes readily ionize to form stable square planar complexes in which the heterocyclic nitrogen coordinates to Pd, whereas in other cases, the acidity of the N–H proton was explored. Finally, activity of complexes as catalysts for aryl amination reactions was also investigated.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::d8395b8ab3032a0349704ebb2fe4e57d https://doi.org/10.1007/s11244-014-0331-3 Zobrazit plný text záznamu Plný text ve formátu PDF