Popis: |
The crystal structure of dichlorobis(2,2′-bis(dimethylarsino)biphenyl)nickel(II) has been determined from single-crystal X-ray diffraction data collected on a two-circle diffractometer. The analysis was carried out on 2542 reflections and refined by full-matrix least-squares calculation to a final R of 0.042. The crystals are triclinic, space group P 1 with a = 15.289(6), b = 11.241(5), c = 10.336(5) A, α = 87.55(4), β = 99.75(5), γ = 102.57(6)° and Z = 2. The complex is monomeric with nickel in a distorted trans-octahedral environment of four arsenic and two chlorine atoms. |