The microwave spectrum of NiH
| Autor: | Jeffrey E. Shirley, Timothy C. Steimle, David F. Nachman, David A. Fletcher, John M. Brown |
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| Rok vydání: | 1990 |
| Předmět: | |
| Zdroj: | Molecular Physics. 69:923-932 |
| ISSN: | 1362-3028 0026-8976 |
| DOI: | 10.1080/00268979000100691 |
| Popis: | Numerous microwave transitions between the Λ-doubling components of vibrational levels in the X 2Δ3/2 (v = 0) state of NiH in the gas phase have been measured using the technique of microwave-optical double resonance (MODR) spectroscopy. An effective experimental method for the simultaneous introduction of low-frequency microwave radiation and optical laser radiation into a flowing reaction chamber has been demonstrated. Some Λ-doubling and magnetic hyperfine parameters were obtained from a least squares fit of an effective hamiltonian model to the observed transition frequencies. The spectroscopic parameters are interpreted in terms of the proposed electronic wavefunctions and state distribution. |
| Databáze: | OpenAIRE |
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