Synthesis and properties of tert-butylphenylmethylene(chloro)phosphorane

Autor:	O. I. Kolodyazhnyi, S. Yu. Sheiko, E. V. Grishkun, A. O. Kolodyazhna, O. O. Kolodyazhna
Rok vydání:	2015
Předmět:	chemistry.chemical_compound Chemistry Organic chemistry Phenol General Chemistry Phosphonium Phosphorane
Zdroj:	Russian Journal of General Chemistry. 85:1639-1643
ISSN:	1608-3350 1070-3632
DOI:	10.1134/s1070363215070117
Popis:	The synthesis and properties of tert-butylphenylmethylene(chloro)phosphorane were described. The prepared chlorophosphorane reacted with alcohols and phenol with the formation of the corresponding phosphonium salts. Its reaction with carbonyl compounds led to the formation of 2-chloro-1,2λ5-oxaphosphetanes, which rearranged providing 2-chloroalkylphosphine oxides or alkenylphosphine oxides.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::d81037bca3648e30b53282b2982505b3 https://doi.org/10.1134/s1070363215070117 Zobrazit plný text záznamu Plný text ve formátu PDF