Doped all-inorganic cesium zirconium halide perovskites with high-efficiency and tunable emission
Autor: | Daoyuan Zheng, Juntao Li, Junxue Liu, Pengfei Cheng, Yuefeng Liu, Ke-Li Han, Yang Yang, Guoxiong Wang, Lu Feng |
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Rok vydání: | 2022 |
Předmět: |
Zirconium
Materials science Photoluminescence business.industry Doping Energy Engineering and Power Technology Halide chemistry.chemical_element Quantum yield Condensed Matter::Materials Science Fuel Technology chemistry Condensed Matter::Superconductivity Electrochemistry Optoelectronics Condensed Matter::Strongly Correlated Electrons business Absorption (electromagnetic radiation) Single crystal Energy (miscellaneous) Perovskite (structure) |
Zdroj: | Journal of Energy Chemistry. 65:600-604 |
ISSN: | 2095-4956 |
DOI: | 10.1016/j.jechem.2021.06.033 |
Popis: | Doping enables manipulation of both the electrical and optical properties of halide perovskites. Herein, we incorporated Te4+ into Cs2ZrCl6 single crystal, simultaneously preserving the vacancy-ordered structure, to obtain an efficient yellow-emitting perovskite with a near-unity photoluminescence quantum yield (PLQY ≈ 97.6%). Te4+ doping modifies the hue and emission color of pristine Cs2ZrCl6, generates new absorption channels, and successfully extends the excitation energy from |
Databáze: | OpenAIRE |
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