Doped all-inorganic cesium zirconium halide perovskites with high-efficiency and tunable emission

Autor: Daoyuan Zheng, Juntao Li, Junxue Liu, Pengfei Cheng, Yuefeng Liu, Ke-Li Han, Yang Yang, Guoxiong Wang, Lu Feng
Rok vydání: 2022
Předmět:
Zdroj: Journal of Energy Chemistry. 65:600-604
ISSN: 2095-4956
DOI: 10.1016/j.jechem.2021.06.033
Popis: Doping enables manipulation of both the electrical and optical properties of halide perovskites. Herein, we incorporated Te4+ into Cs2ZrCl6 single crystal, simultaneously preserving the vacancy-ordered structure, to obtain an efficient yellow-emitting perovskite with a near-unity photoluminescence quantum yield (PLQY ≈ 97.6%). Te4+ doping modifies the hue and emission color of pristine Cs2ZrCl6, generates new absorption channels, and successfully extends the excitation energy from
Databáze: OpenAIRE