Spectroscopy of Bioactive Manganese(II) and Copper(II) Complexes with Mannich Bases

Autor:	I.I. Azarko, Anna T. Gres, N.P. Osipovich, H. I. Harbatsevich, N.V. Loginova, G. I. Polozov, T. V. Koval′chuk
Rok vydání:	2015
Předmět:	Denticity Metal ions in aqueous solution Inorganic chemistry chemistry.chemical_element Infrared spectroscopy Manganese Condensed Matter Physics Copper law.invention Crystallography chemistry Octahedron law Molecule Electron paramagnetic resonance Spectroscopy
Zdroj:	Journal of Applied Spectroscopy. 82:713-718
ISSN:	1573-8647 0021-9037
DOI:	10.1007/s10812-015-0169-x
Popis:	The compositions and geometries of coordination polyhedra in Cu(II) and Mn(II) complexes with Mannich bases were determined using IR, EPR, and electron spectroscopy. It was shown that bidentate ligands were coordinated to the metal ions in these complexes. The coordination polyhedra of mononuclear Cu(II) and Mn(II) complexes consisted of two mono-anionic ligands. Polyhedra of the Mn(II) complexes also contained two water molecules. The Cu(II) complexes had characteristic square-planar [CuN2O2] coordination polyhedra; Mn(II) complexes, [MnN2O4] octahedra.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::d7e3aace32280967c3b85a8061e90b3f https://doi.org/10.1007/s10812-015-0169-x Zobrazit plný text záznamu Plný text ve formátu PDF