Aqueous synthesis and molecular structure of a seven-coordinate complex (η-CH3C5H4)Zr(S2CNBz2)3
| Autor: | Shi-Wei Lu, He-Fu Guo, Ning-Hai Hu, Zhi-Qiang Wang |
|---|---|
| Rok vydání: | 1992 |
| Předmět: |
chemistry.chemical_classification
Zirconium Denticity Ligand Stereochemistry Acetylacetone chemistry.chemical_element Crystal structure Inorganic Chemistry Crystallography chemistry.chemical_compound Pentagonal bipyramidal molecular geometry chemistry X-ray crystallography Materials Chemistry Physical and Theoretical Chemistry Dithiocarbamate |
| Zdroj: | Polyhedron. 11:39-44 |
| ISSN: | 0277-5387 |
| DOI: | 10.1016/s0277-5387(00)83256-8 |
| Popis: | The title complex is conveniently prepared by the reaction of (MeCp)2ZrCl2 (MeCp = η-methylcyclopentadienyl) with 3 equivalents of NaS2CNBz2 in the water phase containing acetylacetone. The crystal and molecular structure of (η-methylcyclopentadienyl)tri(N,N-dibenzylthiocarbamato)zirconium(IV) has been determined by X-ray diffraction. The crystal contains two different seven-coordinate molecules (A and B) which both have pentagonal bipyramidal geometry. The zirconium is attached to one η-methylcyclopentadienyl ligand occupying the axial position. One of the bidentate dithiocarbamate ligands spans the other axial position and one equatorial position; the other two bidentate dithiocarbamato ligands take the remaining equatorial positions (ZrC = 2.509–2.569 A; ZrS = 2.658–2.717 A). |
| Databáze: | OpenAIRE |
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