The Synthesis and Reactions of some Dialkylaminodifluorophosphine Derivatives of the group VI Metal Carbonyls

Autor: J. K. Ruff, W. M. Douglos
Rok vydání: 1972
Předmět:
Zdroj: Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry. 2:151-156
ISSN: 1532-2440
0094-5714
DOI: 10.1080/00945717208069594
Popis: Two convenient syntheses of monosubstituted dialkylarninodifluorophosphine metal pentacarbonyls (metal [dbnd] Cr, Mo and W) are described. Reaction of these materials with anhydrous HBr produced the corresponding bromodifluorophosphine derivatives, BrPF2M(CO)5.
Databáze: OpenAIRE