ChemInform Abstract: Synthesis of New Bis(p-(phenylethynyl)phenyl)hetarylenes and Bis(p-( phenylglyoxalyl)phenyl)hetarylenes

Autor: G. B. Sarkisyan, Nataliya M. Belomoina, A. K. Mikitaev, M. M. Begretov, A. L. Rusanov, Mukhamed L. Keshtov
Rok vydání: 2010
Předmět:
Zdroj: ChemInform. 28
ISSN: 0931-7597
DOI: 10.1002/chin.199714132
Popis: A series of new bis[p-(phenylethynyi)phenyl]hetarylenes was obtained by cross-coupling between heteroaromatic dibromides and phenylacetylene catalyzed by phosphine complexes of palladium in the presence of Cul and an organic base. Bis[p-(phenylethynyl)phe-nyl]hetarylenes were oxidized to the corresponding bis[p-(phenylglyoxalyl)phenylihetarylenes using the I2-DMSO system.
Databáze: OpenAIRE