Laser ablation of ammonium nitrate

Autor: Jane K. Rice, Louise Pasternack
Rok vydání: 1993
Předmět:
Zdroj: The Journal of Physical Chemistry. 97:12805-12810
ISSN: 1541-5740
0022-3654
DOI: 10.1021/j100151a029
Popis: The laser ablation of ammonium nitrate has been studied, with products collected under low-pressure conditions on a cryogenic argon matrix surface. Relative product populations are analyzed using FTIR spectroscopy. Large effects are observed as the laser fluence and wavelengths are changed. Using 1064-nm pulses or low fluences of 532 nm, NH 3 and HNO 3 are most abundant with smaller (or negligible) quantities of NO, NO 2 , and N 2 O. At 266 nm and higher fluences of 532 nm, the reactions produce larger populations of NO, NO 2 , and small amounts of N 2 O
Databáze: OpenAIRE