An in-situ infrared spectroscopic study of the adsorption of citrate on Au(111) electrodes

Autor:	Simon Floate, Karen L. Young, Mir Ghasem Hosseini, David Ritson, Mohammad Reza Arshadi, Richard J. Nichols
Rok vydání:	2003
Předmět:	General Chemical Engineering Inorganic chemistry Infrared spectroscopy Analytical Chemistry chemistry.chemical_compound Adsorption stomatognathic system chemistry Electrochemistry Formate Perchloric acid Point of zero charge Fourier transform infrared spectroscopy Citric acid Electrode potential
Zdroj:	Journal of Electroanalytical Chemistry. 542:67-74
ISSN:	1572-6657
Popis:	The specific adsorption of citrate from perchloric acid electrolytes, has been investigated using in-situ FTIR spectroscopy at Au(111) electrodes. For comparison IR spectra for formate adsorption are also presented. Clear voltammetric peaks have been observed positive of the pzc and these are shown by FTIR spectroscopy to be associated with the adsorption of citrate. Models for the surface co-ordination of the citrate anion are discussed.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::d7866f75996bca53f93d29667ff3d3a7 https://doi.org/10.1016/s0022-0728(02)01451-1 Zobrazit plný text záznamu Full Text from ScienceDirect