Functionalized heteropolyanions: high-valent metal nitrido fragments incorporated into a Keggin polyoxometalate structureElectronic supplementary information (ESI) available: general synthetic and characterization details. See http://www.rsc.org/suppdata/cc/b2/b209173a
Autor: | Anna Proust, Sean R. Tomlinson, Pierre Gouzerh, HaiDoo Kwen, Céline Dablemont, René Thouvenot, Eric A. Maatta |
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Rok vydání: | 2002 |
Předmět: | |
Zdroj: | Chemical Communications. :2970-2971 |
ISSN: | 1364-548X 1359-7345 |
Popis: | Three examples of nitrido-functionalized polyoxometalate species are reported, namely (n-Bu4N)4[PW11O39(OsN)] (1), (n-Bu4N)4[PW11O39(ReN)] (2), and (n-Bu4N)3[PW11O39(ReN)] (3), which feature the incorporation of [OsVIN]3+, [ReVIN]3+ and [ReVIIN]4+ fragments, respectively, into the framework of a Keggin-type heteropolyanion. |
Databáze: | OpenAIRE |
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