Towards panchromatic Fe(ii ) NHC sensitizers via HOMO inversion
| Autor: | Stefan Haacke, Anil Reddy Marri, Thomas Penfold, Bogdan MAREKHA, PHILIPPE GROS |
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| Rok vydání: | 2023 |
| Předmět: | |
| Zdroj: | Inorganic Chemistry Frontiers. 10:118-126 |
| ISSN: | 2052-1553 |
| DOI: | 10.1039/d2qi01903e |
| Popis: | Fused polythiophenes attached to Fe(ii)NHC complexes induced a mixing of the t2g and π HOMO orbitals promoting 80 nm red-shift of the MLCT transition, 3 fold increase of the molar extinction coefficient and 3MLCT excited state lifetime up to 18 ps. |
| Databáze: | OpenAIRE |
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