Towards panchromatic Fe(ii) NHC sensitizers via HOMO inversion

Autor:	Stefan Haacke, Anil Reddy Marri, Thomas Penfold, Bogdan MAREKHA, PHILIPPE GROS
Rok vydání:	2023
Předmět:	Inorganic Chemistry
Zdroj:	Inorganic Chemistry Frontiers. 10:118-126
ISSN:	2052-1553
Popis:	Fused polythiophenes attached to Fe(ii)NHC complexes induced a mixing of the t2g and π HOMO orbitals promoting 80 nm red-shift of the MLCT transition, 3 fold increase of the molar extinction coefficient and 3MLCT excited state lifetime up to 18 ps.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::d76673a58196778fe292e864365ba49a https://doi.org/10.1039/d2qi01903e Zobrazit plný text záznamu