Acid-catalyzed benzoylation reactions of Diels-Alder polyphenylenes
| Autor: | Kwan-Soo Lee, Eric G. Sorte, Cassandria Poirier, Nelson S. Bell, Yu Seung Kim, Cy Fujimoto, Sandip Maurya, Eun Joo Park |
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| Rok vydání: | 2018 |
| Předmět: |
Trifluoromethyl
Polymers and Plastics organic chemicals Organic Chemistry Substituent 02 engineering and technology 010402 general chemistry 021001 nanoscience & nanotechnology 01 natural sciences Chloride Medicinal chemistry 0104 chemical sciences Catalysis Acylation chemistry.chemical_compound Benzoyl chloride chemistry Nucleophilic aromatic substitution Materials Chemistry medicine 0210 nano-technology Triflic acid medicine.drug |
| Zdroj: | Polymer. 158:190-197 |
| ISSN: | 0032-3861 |
| DOI: | 10.1016/j.polymer.2018.10.060 |
| Popis: | Post-polymerization reactions of Diels-Alder polyphenylene with ring-substituted benzoyl chloride derivatives using triflic acid as the catalyst, effected selective Friedel-Crafts acylation of the lateral phenyl groups attached to the polyphenylene backbone. Using 4-(trifluoromethyl) benzoyl chloride gave a polymer with increased hydrophobicity. Using 4-fluorobenzoyl chloride afforded lateral 4-(fluorobenzoyl)phenyl substituents, which were further functionalized by nucleophilic aromatic substitution of the reactive fluoro substituent by 4-methoxyphenol. |
| Databáze: | OpenAIRE |
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