Production of acrolein from glycerol over silica-supported heteropoly acids

Autor:	Eriko Tsukuda, Satoshi Sato, Toshiaki Sodesawa, Ryoji Takahashi
Rok vydání:	2007
Předmět:	Chemistry Process Chemistry and Technology Acrolein General Chemistry Silicotungstic acid medicine.disease Catalysis chemistry.chemical_compound medicine Glycerol Organic chemistry Dehydration Selectivity Mesoporous material Ambient pressure
Zdroj:	Catalysis Communications. 8:1349-1353
ISSN:	1566-7367
Popis:	Dehydration of glycerol to produce acrolein was performed over several solid acids. Supported heteropoly acids were effective as a catalyst for the dehydration of glycerol. The catalytic activity depended on the types of heteropoly acid and on the size of the mesopores in the silica support. Silicotungstic acid supported on silica with mesopores of 10 nm showed the highest catalytic activity with the acrolein selectivity of >85 mol% at an ambient pressure and 275 °C.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::d758c277e28cf0a6fae95b929767b6d8 https://doi.org/10.1016/j.catcom.2006.12.006 Zobrazit plný text záznamu Full Text from ScienceDirect