Study of electronic excitation and electron capture processes in the collision between ground-state rubidium atoms and potassium ions by crossed beams

Autor:	J. de Andrés, J. Sogas, A. Aguilar, M. Albertí, Josep M. Lucas, M. E. Aricha
Rok vydání:	2001
Předmět:	chemistry Electron capture Excited state Ab initio General Physics and Astronomy chemistry.chemical_element Physical and Theoretical Chemistry Atomic physics Ground state Adiabatic process Potential energy Excitation Rubidium
Zdroj:	Physical Chemistry Chemical Physics. 3:3638-3644
ISSN:	1463-9084 1463-9076
DOI:	10.1039/b102390j
Popis:	Collisional processes between K ions and Rb (both in their ground state) have been studied using a crossed beam technique and measuring the decay fluorescence. Emissions corresponding to decay of the first excited state of Rb and the first two excited states of neutral K have been detected. For these, absolute total cross-section dependence on collision energy, branching ratios between J-states and true excitation cross-sections (from polarization measurements) have been determined, all in the 0.3–4.1 keV range. The results are interpreted using adiabatic potential energy curves calculated ab initio employing one-electron, non-empirical, relativistic pseudopotentials and including core polarisation.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::d757832a9c71429a37820674bd7678d2 https://doi.org/10.1039/b102390j Zobrazit plný text záznamu