Commercial Carbonaceous Materials as Lithium Intercalation Anodes
| Autor: | K. Kinoshita, T. D. Tran, X. Song, J. H. Feikert |
|---|---|
| Rok vydání: | 1995 |
| Předmět: |
Renewable Energy
Sustainability and the Environment Scanning electron microscope Inorganic chemistry technology industry and agriculture chemistry.chemical_element Electrolyte Condensed Matter Physics Surfaces Coatings and Films Electronic Optical and Magnetic Materials chemistry.chemical_compound chemistry Propylene carbonate Materials Chemistry Electrochemistry Lithium Graphite Dimethyl carbonate Carbon Ethylene carbonate |
| Zdroj: | Journal of The Electrochemical Society. 142:3297-3302 |
| ISSN: | 1945-7111 0013-4651 |
| DOI: | 10.1149/1.2049977 |
| Popis: | Commercial carbonaceous materials were examined as lithium intercalation anodes in propylene carbonate (carbons) and ethylene carbonate/dimethyl carbonate (graphites) electrolytes. The reversible capacity (180--355 mAh/g) and the irreversible capacity loss (15--200% based on reversible capacity) depends on the type of binder, carbon type, morphology, and phosphorus doping concentration. A carbon-based binder was chosen for electrode fabrication, producing mechanically and chemically stable electrodes and reproducible results. Several types of graphites had capacity approaching LiC{sub 6}. Petroleum fuel green cokes doped with phosphorus gave more than a 20% increase in capacity compared to undoped samples. Electrochemical characteristics are related to scanning electron microscopy, transmission electron microscopy, X-ray diffraction, and Brunauer, Emmett, and Teller method measurements. |
| Databáze: | OpenAIRE |
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