Clusters as ligands: Synthesis, structure and coordination chemistry of ruthenium clusters derived from 4- and 5-ethynyl-2,2′-bipyridine
| Autor: | Paul J. Low, Campbell F. R. Mackenzie, George A. Koutsantonis, Lindsay T. Byrne, Brian W. Skelton, Sören Bock |
|---|---|
| Rok vydání: | 2016 |
| Předmět: |
chemistry.chemical_classification
010405 organic chemistry Organic Chemistry Alkyne chemistry.chemical_element Nuclear magnetic resonance spectroscopy 010402 general chemistry 01 natural sciences Biochemistry Medicinal chemistry 2 2'-Bipyridine 0104 chemical sciences 3. Good health Coordination complex Ruthenium Inorganic Chemistry chemistry.chemical_compound chemistry Materials Chemistry Proton NMR Organic chemistry Moiety Physical and Theoretical Chemistry Bimetallic strip |
| Zdroj: | Journal of Organometallic Chemistry. 812:190-196 |
| ISSN: | 0022-328X |
| Popis: | The reaction of [Ru3(CO)10(μ-dppm)] (1) with 4-ethynyl-2,2′-bipyridine (2) or 5-ethynyl-2,2′-bipyridine (3) affords the Ru3C2 clusters [Ru3(μ-H)(μ3-C2bpy)(CO)7(dppm)] (bpy = 4-bpy, 4 (22%); bpy = 5-bpy, 5 (55%)). Complexes 4 and 5 have been fully characterised by NMR spectroscopy, with 2D-COSY methods being used to aid 1H NMR assignments, and single crystal X-ray diffraction. The pendant bipyridyl moiety presents as a site for further reaction using the ‘Tinkertoy’ approach, and subsequent reactions of 4 and 5 with PdCl2(NCPh)2 affords the bimetallic complexes [Ru3(μ-H){μ3-C2bpy(κ2-N′,N–PdCl2)}(CO)7(dppm)] bpy = 4-bpy, 6 (55%); bpy = 5-bpy, 7 (35%)). |
| Databáze: | OpenAIRE |
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