Oxidation of benzyl alcohols to the corresponding carbonyl compounds catalyzed by copper (II) meso-tetra phenyl porphyrin as cytochrome P-450 model reaction
| Autor: | Mohammad Reza Naimi-Jamal, Rahmatolah Rahimi, Ensieh Gholamrezapor |
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| Rok vydání: | 2011 |
| Předmět: |
inorganic chemicals
Cytochrome biology organic chemicals High selectivity chemistry.chemical_element biology.organism_classification Copper Porphyrin Catalysis Inorganic Chemistry chemistry.chemical_compound chemistry Polymer chemistry polycyclic compounds Materials Chemistry biology.protein Tetra Organic chemistry heterocyclic compounds Molecular oxygen Physical and Theoretical Chemistry Isobutyraldehyde |
| Zdroj: | Inorganic Chemistry Communications. 14:1561-1568 |
| ISSN: | 1387-7003 |
| Popis: | The oxidation of benzyl alcohols has been studied in the presence of isobutyraldehyde as co-catalyst, molecular oxygen as oxidant and copper (II) meso-tetra phenyl porphyrin (CuTPP) as catalyst. The CuTPP catalyst exhibits good activity and high selectivity under mild conditions. The effects of temperature and solvents have also been investigated in this catalyst system. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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