Bisurea and Bisthiourea H-Bonding Organocatalysts for Ring-Opening Polymerization: Cues for the Catalyst Design
Autor: | Elizabeth T. Kiesewetter, Rukshika S. Hewawasam, U. L. D. Inush Kalana, Timothy J. Bannin, Nayanthara U. Dharmaratne, Thomas J. Wright, Matthew K. Kiesewetter |
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Rok vydání: | 2019 |
Předmět: |
chemistry.chemical_classification
Polymers and Plastics Base (chemistry) Chemistry Hydrogen bond Organic Chemistry Thio 02 engineering and technology 010402 general chemistry 021001 nanoscience & nanotechnology 01 natural sciences Ring-opening polymerization 0104 chemical sciences Catalysis Inorganic Chemistry chemistry.chemical_compound Polymerization Polymer chemistry Materials Chemistry Urea 0210 nano-technology |
Zdroj: | Macromolecules. 52:9232-9237 |
ISSN: | 1520-5835 0024-9297 |
DOI: | 10.1021/acs.macromol.9b01875 |
Popis: | A series of conformationally flexible bis(thio)urea H-bond donors plus base cocatalyst were applied to the ring-opening polymerization (ROP) of lactones. The rate of the ROP displays a strong depen... |
Databáze: | OpenAIRE |
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