| Autor: |
K. Rahkamaa-Tolonen, D. Yu. Murzin, Johan Wärnå, Henrik Backman, Tapio Salmi |
| Rok vydání: |
2005 |
| Předmět: |
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| Zdroj: |
Chemical Engineering Journal. 107:89-95 |
| ISSN: |
1385-8947 |
| DOI: |
10.1016/j.cej.2004.12.014 |
| Popis: |
The isotopic exchange between hydrogen and deuterium was studied over a Pd/alumina catalyst. A model was proposed, including the adsorption and dissociation of hydrogen and deuterium. An adsorption-assisted desorption mechanism was also included and turned out to play a minor role in the H 2 /D 2 exchange but have to be considered in the reaction between deuterium and water. A comparison between the experimental data and the simulation revealed that the model could describe the observed dissociation and isotope exchange reaction. |
| Databáze: |
OpenAIRE |
| Externí odkaz: |
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