Hydrogen-peroxide-initiated polymerization of isoprene in alcohol solutions

Autor:	V. K. Grishchenko, Tamara S. Dmitrieva, Vitaly Boiko, Tatiana S. Yatsimirskaya, Svistova Elena I, Valery I. Valuev
Rok vydání:	1992
Předmět:	Telechelic polymer Polymers and Plastics Radical polymerization Solution polymerization General Chemistry Oligomer humanities Surfaces Coatings and Films chemistry.chemical_compound Monomer chemistry Polymerization Polymer chemistry Materials Chemistry Organic chemistry Hydrogen peroxide Isoprene
Zdroj:	Journal of Applied Polymer Science. 46:2081-2087
ISSN:	1097-4628 0021-8995
DOI:	10.1002/app.1992.070461203
Popis:	The radical polymerization of isoprene in alcohol solutions initiated by hydrogen peroxide was studied. It was found that alcohols were components of the initiated system and that their fragments with hydroxyl groups were included in every second molecule of an oligomer irrespective of the type of alcohol, of the monomer conversion, and of the oligomer molecular weight. The oligomer yields and its molecular weight were determined by alcohols through their effect upon the phase state of polymerization systems. © 1992 John Wiley & Sons, Inc.
Databáze:	OpenAIRE
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