Vibrational spectroscopy and the intermolecular dynamics of condensed states VI. Temperature dependence of the intermolecular spectra for toluene, quinoline, and PCl3

Autor: N. G. Torgunakov, A. V. Sechkarev, P. T. Nikolaenko, B. P. Nerzorov
Rok vydání: 1972
Předmět:
Zdroj: Soviet Physics Journal. 15:207-209
ISSN: 1573-9228
0038-5697
DOI: 10.1007/bf00819434
Popis: The spectra have been examined for the polycrystalline and liquid states; the temperature ranges for orientation melting have been measured, as has the temperature range for the polymorphic transition in toluene. It is found that orientation ordering occurs in liquid quinoline near the usual melting point, and a short-range order structure is assumed. The behavior of toluene shows marked thermal hysteresis in the range from −50 to −150 ° C.
Databáze: OpenAIRE