Complex formation between polymethacrylic acid and copolymers of adipic acid with poly(ethylene glycol) in aqueous solution
Autor: | V.Yu. Baranovsky, S. Shenkov, V. Doseva |
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Rok vydání: | 1997 |
Předmět: |
chemistry.chemical_classification
congenital hereditary and neonatal diseases and abnormalities Materials science Aqueous solution Adipic acid Polymers and Plastics Organic Chemistry nutritional and metabolic diseases hemic and immune systems Polymer Polyelectrolyte Hydrophobic effect enzymes and coenzymes (carbohydrates) chemistry.chemical_compound chemistry immune system diseases PEG ratio Polymer chemistry Materials Chemistry Copolymer Ethylene glycol |
Zdroj: | Polymer. 38:1339-1344 |
ISSN: | 0032-3861 |
DOI: | 10.1016/s0032-3861(96)00550-2 |
Popis: | The complex formation between polymethacrylic acid (PMAA) and the copolymers of adipic acid (AdA) with poly(ethylene glycol) (PEG) in dilute solution has been studied. The hydrophobic AdA fragments break the continuous cooperative hydrogen bonds between the polymer components in the polycomplex being however the factor that stabilizes the polycomplex (PMAA.AdA/PEG). If the AdA/PEG copolymers are of one and the same chain length the copolymer having more AdA hydrophobic fragments exhibits greater complex forming ability. |
Databáze: | OpenAIRE |
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