beta.-Hydride elimination from methoxo vs. ethyl ligands: thermolysis of (DPPE)Pt(OCH3)2, (DPPE)Pt(CH2CH3)(OCH3) and (DPPE)Pt(CH2CH3)2

Autor:	Henry E. Bryndza, Joseph C. Calabrese, D. Christopher Roe, Marianne Marsi, John E. Bercaw, Wilson Tam
Rok vydání:	1986
Předmět:	Colloid and Surface Chemistry Chemistry Thermal decomposition Organic chemistry General Chemistry Beta-Hydride elimination Biochemistry Medicinal chemistry Catalysis
Zdroj:	Journal of the American Chemical Society. 108:4805-4813
ISSN:	1520-5126 0002-7863
DOI:	10.1021/ja00276a018
Popis:	La decomposition de (dppe)Pt(OCH 3 ) 2 a 25° donne un melange de methanol, oligomeres de formaldehyde et un peu de CO. Le complexe (dppe)Pt(CH 2 CH 3 )(OCH 3 ) se decompose en un melange de C 2 H 4 , C 2 H 6 , methanol et oligomeres de formaldehyde a 100°C
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::d6b1faf2fda2c2f436055fd2a37434c3 https://doi.org/10.1021/ja00276a018