Stereoselective fluorination of methylenecyclopropanes with N-F reagents: A modular entry to γ-fluorohomoallylic sulfonimides and γ-fluorohomoallylic amides

Autor:	Weijun Fu, Dongsheng Deng, Mei Zhu, Baoming Ji, Dongfeng Hong, Chen Xun, Guanglong Zou
Rok vydání:	2009
Předmět:	Inorganic Chemistry chemistry.chemical_compound Chemistry Reagent Organic Chemistry Environmental Chemistry Organic chemistry Stereoselectivity Physical and Theoretical Chemistry Selectfluor Biochemistry
Zdroj:	Journal of Fluorine Chemistry. 130:996-1000
ISSN:	0022-1139
DOI:	10.1016/j.jfluchem.2009.07.020
Popis:	A convenient and efficient method for fluorination of methylenecyclopropanes is reported. This is exemplified in the stereoselective preparation of N-[(E)-3-fluorobut-3-en-1-yl]-benzenesulfonimides by the reaction of methylenecyclopropanes with N-fluorobenzenesulfonimide in good to excellent yields. Moreover, γ-fluorohomoallylic amides are synthesized using Selectfluor in R3CN at 60 °C.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::d6a9d4ac777fadc8915582daf9ca6e8e https://doi.org/10.1016/j.jfluchem.2009.07.020 Zobrazit plný text záznamu Full Text from ScienceDirect