ChemInform Abstract: Copper(I) Complexes Bearing Carbenes Beyond Classical N-Heterocyclic Carbenes: Synthesis and Catalytic Activity in 'Click Chemistry'

Autor:	David B. Cordes, Alexandra M. Z. Slawin, Mathieu Lesieur, Catherine S. J. Cazin, Kasun S. Athukorala Arachchige, Fady Nahra, Yannick D. Bidal, Mohand Melaimi, Guy Bertrand
Rok vydání:	2016
Předmět:	chemistry.chemical_compound Copper oxide chemistry Mesoionic Click chemistry chemistry.chemical_element Iminium General Medicine Copper Carbene Combinatorial chemistry Cycloaddition Catalysis
Zdroj:	ChemInform. 47
ISSN:	0931-7597
DOI:	10.1002/chin.201610150
Popis:	The synthesis and characterization of abnormal N-heterocyclic carbene, cyclic (alkyl)(amino)carbene, and mesoionic carbene copper(I) complexes are reported. These organometallic species are obtained via a versatile and inexpensive synthetic pathway using readily available reactants, namely copper oxide and iminium salts. The catalytic activity of this series of complexes was evaluated in the [3+2] cycloaddition of alkynes with azides (CuAAC). Outstanding catalytic properties were observed for the abnormal NHC- and triazolylidene-based copper(I) complexes.
Databáze:	OpenAIRE
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