Influence of betaine benzyl ester on the controlled potential electrolysis of benzyl bromides on platinum electrode in acetonitrile

Autor:	Roger N. Renaud, Denis Bérubé, G. Pierre
Rok vydání:	1983
Předmět:	Electrolysis General Chemical Engineering Inorganic chemistry chemistry.chemical_element Protonation Electrochemistry Medicinal chemistry law.invention chemistry.chemical_compound Betaine chemistry law Yield (chemistry) Ammonium Acetonitrile Platinum
Zdroj:	Electrochimica Acta. 28:1367-1371
ISSN:	0013-4686
DOI:	10.1016/0013-4686(83)85190-1
Popis:	An exploratory study of the electrochemical reduction of benzyl bromides is performed on a preparative scale using a platinum electrode in acetonitrile in the presence of ammonium salts. This work shows that the presence of derivatives of betaine increases the yield of dimerization products at the expense of protonation products. These salts allow the reduction of benzyl bromides at more positive potentials.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::d676e274640eb0a4f99c94dcf5e11fc3 https://doi.org/10.1016/0013-4686(83)85190-1 Zobrazit plný text záznamu