New Pr and Nd complexes containing TCNQ radicals

Autor:	Kinga Suwinska, Mariana Mitewa, M. Fonari, Cristina Vico Alonso, Loreto Ballester, M.F. Perpiñán, Angel Gutiérrez
Rok vydání:	2001
Předmět:	Reaction conditions Lanthanide medicine.diagnostic_test Chemistry Mechanical Engineering Radical Inorganic chemistry Metals and Alloys Infrared spectroscopy Chemical synthesis Crystallography Delocalized electron Mechanics of Materials Spectrophotometry Materials Chemistry medicine Hydrate
Zdroj:	Journal of Alloys and Compounds. :138-141
ISSN:	0925-8388
DOI:	10.1016/s0925-8388(01)01105-7
Popis:	New compounds formed by reaction of TCNQ lanthanide complexes containing N-donor ligands have been obtained. By controlling the reaction conditions, different compounds of formulae Ln(N–N)x(TCNQ)3 (Ln=Pr, Nd; N–N=1,10-phenanthroline, dipyridylamine; x=2, 4) and Ln(N–N)4(TCNQ)4 are isolated. The former have only TCNQ anions neutralizing the lanthanide charge, while the latter exhibit electronic delocalization, as reflected by their semiconducting behavior.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::d6743abb4ef582a7dbbca0d4dd44f1de https://doi.org/10.1016/s0925-8388(01)01105-7 Zobrazit plný text záznamu Full Text from ScienceDirect