Homolytic reactions of N-bromohexamethyldisilazane with trialkyl(phenylalkoxy) derivatives of silicon and tin
Autor: | M. G. Voronkov, T. A. Podgorbunskaya, V. I. Rakhlin |
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Rok vydání: | 2010 |
Předmět: | |
Zdroj: | Russian Journal of General Chemistry. 80:930-935 |
ISSN: | 1608-3350 1070-3632 |
Popis: | The main product of the photoinduced reaction of N-bromohexamethyldisilazane with trialkyl-(benzyloxy)derivatives of silicon and tin R3MO(CH2) n Ph (R = Me, Et; M = Si, Sn; n = 1) is N,N-dibenzylidene-C-phenylmethanediamine (hydrobenzamide). For M = Si, with increase of the length of the methylene chain between the oxygen atom and the phenyl group (n = 2, 3), the similar reaction affords the product of bromination of the benzylic carbon atom R3MO(CH2)n−1CHBrPh. For M = Sn, the reaction results in the formation of 2-phenyloxacycloalkanes PhCHO(CH2)n−1. |
Databáze: | OpenAIRE |
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