Homolytic reactions of N-bromohexamethyldisilazane with trialkyl(phenylalkoxy) derivatives of silicon and tin

Autor:	M. G. Voronkov, T. A. Podgorbunskaya, V. I. Rakhlin
Rok vydání:	2010
Předmět:	Hexamethyldisiloxane Silicon Halogenation chemistry.chemical_element General Chemistry Photochemistry Medicinal chemistry Stannane Homolysis chemistry.chemical_compound chemistry Phenyl group Methylene Tin
Zdroj:	Russian Journal of General Chemistry. 80:930-935
ISSN:	1608-3350 1070-3632
Popis:	The main product of the photoinduced reaction of N-bromohexamethyldisilazane with trialkyl-(benzyloxy)derivatives of silicon and tin R3MO(CH2) n Ph (R = Me, Et; M = Si, Sn; n = 1) is N,N-dibenzylidene-C-phenylmethanediamine (hydrobenzamide). For M = Si, with increase of the length of the methylene chain between the oxygen atom and the phenyl group (n = 2, 3), the similar reaction affords the product of bromination of the benzylic carbon atom R3MO(CH2)n−1CHBrPh. For M = Sn, the reaction results in the formation of 2-phenyloxacycloalkanes PhCHO(CH2)n−1.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::d66d2c08250d22a46e4d4f0576f5af6b https://doi.org/10.1134/s1070363210050117 Zobrazit plný text záznamu Plný text ve formátu PDF