Enantioselective Desymmetrization of Prochiral Cyclopentene-1,3-diones Triggered by Remote C(sp2)–N Bond Formation

Autor:	Ashok Donthoju, Nemali Manjula, Rambabu Chegondi, Lakshmi Revati Magham, Neetu Singh
Rok vydání:	2019
Předmět:	chemistry.chemical_compound chemistry 010405 organic chemistry Stereochemistry Organic Chemistry Enantioselective synthesis Cyclopentene Bond formation 010402 general chemistry 01 natural sciences Desymmetrization 0104 chemical sciences
Zdroj:	The Journal of Organic Chemistry. 84:15735-15744
ISSN:	1520-6904 0022-3263
DOI:	10.1021/acs.joc.9b02411
Popis:	The enantioselective desymmetrization via remote C(sp2)–H amidation of the prochiral 2,2-disubstituted cyclopentene-1,3-dione with N-methoxybenzamide has been developed. The overall process was cat...
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::d666e196789414148df6e88f7392e31d https://doi.org/10.1021/acs.joc.9b02411 Zobrazit plný text záznamu