An environmentally benign benzylic oxidation catalyzed by hypervalent iodine intermediate in water

Autor:	Jian Tao Hu, Jie Yan, Yuan Xu
Rok vydání:	2012
Předmět:	chemistry.chemical_compound Chemistry Potassium bromide Iodobenzene Hypervalent molecule chemistry.chemical_element Radical initiator Organic chemistry General Chemistry Iodine Medicinal chemistry Catalysis
Zdroj:	Chinese Chemical Letters. 23:891-894
ISSN:	1001-8417
DOI:	10.1016/j.cclet.2012.06.002
Popis:	An effective and environmentally benign benzylic oxidation for transition of alkylarenes into the corresponding carbonyl compounds was reported. Alkylarenes were mixed and stirred with potassium bromide, m -chloroperbenzoic acid and a catalytic amount of iodobenzene in water at 60 °C for several hours, a series of the corresponding carbonyl compounds was obtained in moderate to good yields. In the reaction, iodobenzene was first oxidized by m -chloroperbenzoic acid into the hypervalent iodine intermediate which then reacted with potassium bromide to form the key radical initiator for the benzylic oxidation.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::d65a743763d58565df5e0eefc42f7244 https://doi.org/10.1016/j.cclet.2012.06.002 Zobrazit plný text záznamu Full Text from ScienceDirect