Oxidative dehydrogenation of propane by molecular chlorine

Autor:	Anton S. Shalygin, Valentin N. Parmon, Vasily V. Kaichev, E.A. Paukshtis, T.S. Glazneva, N.V. Testova
Rok vydání:	2015
Předmět:	Aqueous solution Process Chemistry and Technology Inorganic chemistry chemistry.chemical_element Hydrochloric acid Catalysis Ruthenium chemistry.chemical_compound chemistry Propane Chlorine Dehydrogenation Incipient wetness impregnation
Zdroj:	Applied Catalysis A: General. 505:441-446
ISSN:	0926-860X
Popis:	The gas-phase oxidative dehydrogenation of propane by molecular chlorine was studied in a flow reactor with a fixed catalyst bed using a series of ruthenium–titania catalysts at temperatures between 150 and 450 °C. It was found that Ru/TiO2 catalyst prepared by the incipient wetness impregnation of titania with an aqueous hydrochloric acid solution of K4[Ru2OCl10] revealed the highest catalytic activity. The selectivity toward propylene reached 95% at the propane conversion of 50% and the complete conversion of chlorine at 400 °C. Propane consumption turnover frequency was 45 10−3 s−1 which is comparable with the highest known values obtained at the oxidative dehydrogenation of propane. Diffuse reflectance UV–vis spectroscopy and X-ray photoelectron spectroscopy study showed that ruthenium oxychloride was the active component of the catalyst.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::d6420831fad41cd90b5670cc818776ed https://doi.org/10.1016/j.apcata.2015.05.018 Zobrazit plný text záznamu Full Text from ScienceDirect