Enantioselective synthesis of the bicyclo[4.3.0]nonane ring system of the pinguisane-type sesquiterpenoids via a Brønsted acid promoted transannular enol alkylation

Autor:	Richard J. G. Black, Alexander J. Blake, Paul A. Clarke
Rok vydání:	2006
Předmět:	chemistry.chemical_classification Bicyclic molecule Chemistry Alkene Stereochemistry Organic Chemistry Enantioselective synthesis Alkylation Ring (chemistry) Biochemistry Enol chemistry.chemical_compound Drug Discovery Nonane Brønsted–Lowry acid–base theory
Zdroj:	Tetrahedron Letters. 47:1453-1455
ISSN:	0040-4039
Popis:	The bicyclo[4.3.0]nonane ring system of the pinguisane-type sesquiterpenoid natural products, including the vicinal quaternary stereocentres, has been synthesised as a single enantiomer via a novel Bronsted acid promoted transannular alkylation of an enol with an unactivated alkene.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::d616e95a971e1e9e5af456f4fb46b12a https://doi.org/10.1016/j.tetlet.2005.12.084 Zobrazit plný text záznamu Full Text from ScienceDirect