Synthesis and spectral properties of the metallophthalocyanines with the fragments of substituted pyrazoles

Autor:	G. P. Shaposhnikov, T. V. Tikhomirov, R. A. Badaukaite, V. P. Kulinich
Rok vydání:	2013
Předmět:	chemistry.chemical_compound chemistry Elemental analysis General chemistry Ligand Polymer chemistry Phthalocyanine Proton NMR General Chemistry Pyrazole Mass spectrometry Photochemistry Electron spectroscopy
Zdroj:	Russian Journal of General Chemistry. 83:744-751
ISSN:	1608-3350 1070-3632
DOI:	10.1134/s1070363213040233
Popis:	By the reaction of 4-bromphthalonitrile with corresponding 1-phenyl-3-methyl-5-hydroxy- and 1-p-sulfophenyl-3-methyl-5-oxypyrazolaes the substituted phthalonitriles were synthesized and converted into metallophthalocyanines with the fragments of substituted pyrazoles. The compounds obtained were identified using the data of elemental analysis, gas chromatography-mass spectrometry, IR, 1H NMR, and electronic spectroscopy. The influence of the peripheral environment of the phthalocyanine ligand in the resulting metal complexes on the spectral and other properties of the latter was revealed.
Databáze:	OpenAIRE
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