Some theoretical aspects on morphology development in seeded composite latexes. I. Batch conditions below monomer saturation
| Autor: | Y. G. J. Durant, Jean Guillot |
|---|---|
| Rok vydání: | 1993 |
| Předmět: |
chemistry.chemical_classification
Polymers and Plastics Chemistry Thermodynamic equilibrium Composite number Emulsion polymerization Polymer Condensed Matter::Soft Condensed Matter Surface tension chemistry.chemical_compound Colloid and Surface Chemistry Monomer Chemical engineering Emulsion Polymer chemistry Materials Chemistry Physical and Theoretical Chemistry Saturation (chemistry) |
| Zdroj: | Colloid & Polymer Science. 271:607-615 |
| ISSN: | 1435-1536 0303-402X |
| DOI: | 10.1007/bf00657992 |
| Popis: | In seeded emulsion polymerization, during the second stage, new interfaces appear and the surface area changes. A thermodynamic equilibrium approach is presented which predicts particle morphology of a whole range of non-spherical particles upon polymer conversion. Simulation takes into account swelling ratio, molar volumes and interfacial tension. As the particle geometry is complex, a new mathematical procedure is detailed. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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