The study of aluminum soap-hydrocarbon systems: Effect of additives and metathesis
| Autor: | Gerould H. Smith, Lockhart B. Rogers, Karol J. Mysels |
|---|---|
| Rok vydání: | 1949 |
| Předmět: |
0301 basic medicine
chemistry.chemical_classification 030109 nutrition & dietetics General Chemical Engineering Organic Chemistry chemistry.chemical_element 04 agricultural and veterinary sciences Metathesis 040401 food science body regions 03 medical and health sciences chemistry.chemical_compound 0404 agricultural biotechnology Hydrocarbon chemistry Aluminium Organic chemistry Benzene |
| Zdroj: | Journal of the American Oil Chemists' Society. 26:135-138 |
| ISSN: | 0003-021X |
| DOI: | 10.1007/bf02665176 |
| Popis: | Many additives have pronounced and manifold effects on the behavior of aluminum soaps-hydrocarbon systems. Some additives accelerate the formation of jellies, other retard it. Some thicken the jellies, others liquefy them. The mechanism of the action of additives is probably manifold, too. One of the many possible mechanisms is that of metathesis between the fatty acid radical of the soap and acidic additives. The actual occurrence of such metathesis is demonstrated by both qualitative observations of a variety of systems and by the preparation in benzene of aluminum dibenzoate from the dilaurate. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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