PVC miniemulsion polymerization. I. Origin of droplet families

Autor:	R. C. Dewald, L. H. Hart, W. F. Carroll
Rok vydání:	1984
Předmět:	Miniemulsion chemistry.chemical_compound Polyvinyl chloride Monomer Materials science chemistry Polymerization Plastisol technology industry and agriculture Emulsion polymerization Particle size Composite material Homogenization (chemistry)
Zdroj:	Journal of Polymer Science: Polymer Chemistry Edition. 22:2923-2930
ISSN:	1542-9369 0360-6376
DOI:	10.1002/pol.1984.170221115
Popis:	A soap/alcohol miniemulsion in combination with an homogenized mixture of monomer and initiator is utilized to generate PVC plastisol. Droplet distributions generated consist of two distinct types. Judicious control of soap-to-alcohol ratio allows control of the number and size of the smaller droplet family; homogenization and initiator water solubility affect the other. Final latex particle distribution may be unimodal or bimodal depending upon manipulation of these factors.
Databáze:	OpenAIRE
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