Hydrothermal Synthesis, Crystal Structure and Spectroscopic Characterization of a Novel 2D → 3D Parallel Polycatenated Coordination Framework [Cd(cmb)(bix)] n

Autor: Ya-Ping Duan, Dongsheng Li, Jun Zhao, Ya-Pan Wu, Jing-Jing Yang, Liang Bai
Rok vydání: 2013
Předmět:
Zdroj: Journal of Inorganic and Organometallic Polymers and Materials. 23:1341-1346
ISSN: 1574-1451
1574-1443
Popis: A novel entangled coordination polymer [Cd(cmb)(bix)] n (1) [H2cmb = 2,2′-(2-(carboxymethoxy)benzoic acid), bix = 1,4-bis(imidazol-1-ylmethyl)benzene], has been synthesized by hydrothermal reaction of Cd(Ac)2·2H2O, bix and H2cmb, and characterized by elemental analysis, IR spectra, PXRD, and single-crystal X-ray diffraction. The structure determination reveals that the complex 1 shows a new 2D → 3D parallel polycatenation framework based on highly undulating 2D 44 -sql layers, in which each layer is polycatenated with adjacent two others (one above and one below, DOC = 4) which have parallel but not coincident mean planes. Moreover, the thermal stability and photoluminescence property of 1 were also discussed. A novel 2D → 3D parallel polycatenated coordination polymer [Cd(cmb)(bix)] n (1), based on highly undulating 2D 44 -sql layers, has been hydrothermally synthesized and characterized. Moreover, the thermal stability and photoluminescence property of 1 were also investigated.
Databáze: OpenAIRE
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