Reactions of 2-Arylthio- and 2-Arylsulfonyl-1-nitro-1-phenylethenes with Amines

Autor:	N. V. Kuz'mina, G. A. Berkova, E. S. Lipina, T. Yu. Kropotova, Z. F. Pavlova
Rok vydání:	2003
Předmět:	Substitution reaction Primary (chemistry) Chemistry Nitro Organic chemistry Amine gas treating General Medicine Cyclic amines
Zdroj:	ChemInform. 34
ISSN:	1522-2667 0931-7597
DOI:	10.1002/chin.200328057
Popis:	2-Arylthio- and 2-arylsulfonyl-1-nitro-1-phenylethenes react with amines to give the corresponding nitroenamines whose configuration (E or Z) depends on the amine structure. Primary amines gives rise to Z-nitroenamines, secondary cyclic amines with 2-arylthio-1-nitroalkenes form E-nitroenamines, and with more reactive 2-arylsulfonyl-1-nitroalkenes E/Z-isomeric mixtures are obtained.
Databáze:	OpenAIRE
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